A Palladium-Catalyzed Construction of Enantiomerically Pure α-Methylene-γ-butyrolactones. Enantiospecific Synthesis of Both Enantiomers of Methylenolactocin

DOI: 10.1016/0957-4166(95)00096-8

Source and publish data:

Tetrahedron Asymmetry p. 885 - 892 (1995)

Update date:2022-08-02

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Authors:

Zhu, Guoxin

Lu, Xiyan

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Article abstract of DOI:10.1016/0957-4166(95)00096-8

Optically active β,γ-disubstituted-α-methylene-γ-butyrolactones were synthesized by palladium(II)-catalyzed cyclization reactions of homochiral allylic 2-alkynoates.The reaction was applied to the total synthesis of methylenolactocin in both enantiomeric

Full text of DOI:10.1016/0957-4166(95)00096-8

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