Tetrahedron Letters p. 123 - 126 (1981)
Update date:2022-08-05
Topics:
Kurebayashi, Yasuo
Ishikawa, Yoshiharu
Terao, Yoshiyasu
Sekiya, Minoru
The finding of a new rearrangement of alkyl (N-alkylamido)methyl sulfide promoted by strong bases such as NaH, LDA and t-BuLi is described.The reaction induces a migration of the alkyl group linked to the sulfur to the amide carbonyl giving the corresponding ketone.
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Doi:10.1055/s-1981-29401
(1981)Doi:10.1016/S0008-6215(00)84690-X
(1981)Doi:10.1016/S0040-4039(01)92530-4
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(2020)Doi:10.1039/c5ta03835a
(2015)Doi:10.1021/acs.joc.6b01370
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