THE γ-ALKYLATION OF ENONES USING SILYL DIENOL ETHERS: THE EFFECT OF CHANGING THE ELECTROPHILE AND OF CHANGING THE SILYL GROUP

DOI: 10.1016/S0040-4039(01)92530-4

Source and publish data:

Tetrahedron Letters p. 705 - 708 (1981)

Update date:2022-08-05

Topics:

Authors:

Fleming, Ian

Lee, Thomas V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)92530-4

Phenylthiomethyl chloride (3) and the trimethylsilyl dienol ether (2) of crotonophenone react to give the lowest level of γ-attack of a range of carbon electrophiles and trimethylsilyl dienol ethers; the γ-selectivity for this reaction can be raised from

Full text of DOI:10.1016/S0040-4039(01)92530-4

Products guided by the article

Product name:(E)-5-Methoxy-5-methyl-1-phenyl-hex-2-en-1-one

Cas No:77987-27-0

R&D Labs maybe for 77987-27-0

Refine Chemicals Science & Technology Technology Developing Co., Ltd.

Contact:+86-22-87899130

Address:No.12,west keyan road,Tianjin City
Changsha Yonta Industry Co., Ltd.

Contact:+ 86-731-8535 2228

Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
Hangzhou Pharma & Chem Co.,Ltd.

Contact:+86-571-87040515

Address:No,139Qingchun Rd
Chinese Peptide Company

Contact:86-571-86737118-8689

Address:No.69, 12 Street, HEDA, Hangzhou, Zhejiang, China
Shanghai Taibao Pharmaceutical Technology Co., Ltd(expird)

Contact:021-52217366

Address:shanghai

Relevant to this article

Reactions of Carbonyl Compounds with Tervalent Phosphorus Reagents. Part 11. A Re-examination of the Reaction of Benzaldehyde with Phosphorus Trichloride in the Presence of Acetic Anhydride

Doi:10.1039/P19810000785
(1981)
A stereospecific synthesis of vinelose

Doi:10.1016/S0008-6215(00)85931-5
(1981)
Computational design of a red fluorophore ligase for site-specific protein labeling in living cells

Doi:10.1073/pnas.1404736111
(2014)
Conformational preferences and supramolecular aggregation in 2-nitrophenylthiolates: Disulfides and thiosulfonates

Doi:10.1107/S0108768100007114
(2000)
A short synthesis of the HIV-protease inhibitor nelfinavir via a diastereoselective addition of ammonia to the α,β-unsaturated sulfoxide derived from (R)-glyceraldehyde acetonide

Doi:10.1016/S0040-4039(02)02077-4
(2002)
Studies of the sclerotization of insect cuticle. The structure of a dimeric product formed by incubation of N-acetyldopamine with locust cuticle

Doi:10.1016/0040-4020(80)80172-4
(1980)

Article Doi