THE γ-ALKYLATION OF ENONES USING SILYL DIENOL ETHERS: THE EFFECT OF CHANGING THE ELECTROPHILE AND OF CHANGING THE SILYL GROUP

DOI: 10.1016/S0040-4039(01)92530-4

Source and publish data:

Tetrahedron Letters p. 705 - 708 (1981)

Update date:2022-08-05

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Authors:

Fleming, Ian

Lee, Thomas V.

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Article abstract of DOI:10.1016/S0040-4039(01)92530-4

Phenylthiomethyl chloride (3) and the trimethylsilyl dienol ether (2) of crotonophenone react to give the lowest level of γ-attack of a range of carbon electrophiles and trimethylsilyl dienol ethers; the γ-selectivity for this reaction can be raised from

Full text of DOI:10.1016/S0040-4039(01)92530-4

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