Journal of Organic Chemistry p. 3181 - 3186 (1981)
Update date:2022-08-02
Topics:
Quirk, Roderic P.
Gambill, Charles R.
Thyvelikakath, George X.
Alkoxycarbenium ions were synthesized by direct O-alkylation of the corresponding carbonyl compounds with trimethyloxonium ion salts and methyl fluorosulfate.The thermodynamic stabilities of the alkoxycarbenium ions were determined by stepwise equilibrations of pairs of these ions via transalkylation with the corresponding carbonyl compounds in liquid sulfur dioxide as monitored by 1H NMR.The structures, spectra, and stabilities of alkoxycarbenium ions have been compared with those of the corresponding hydroxycarbenium ions.In general, the relative stability order for alkoxycarbenium ions parallels the order of stabilities for the corresponding hydroxycarbenium ions.
View MoreContact:+33-5-34012600
Address:28 ZA des Pignès
Shanghai Hohance Chemical Co., ltd
Contact:13914753421
Address:Fl.5;Bld. 70, Lane 1500; Xinfei Road
Contact:0571-
Address:zhejing
Jiangsu Wanlong Chemical Co., Ltd.
website:http://www.wanlongchem.com
Contact:+86-511-86810993 0086-511-8681 0888;
Address:Quanzhou Town, Danyang City, Jiangsu
Contact:86+21-56421993
Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
Doi:10.1021/jm00147a043
(1985)Doi:10.1016/S0008-6215(00)84580-2
(1980)Doi:10.1246/cl.1981.279
(1981)Doi:10.1002/ardp.19973301208
(1997)Doi:10.1007/BF00507237
(1981)Doi:10.1021/jo00330a008
(1981)