Sulphide Extrusion from Methyl Sulphonium Salts of the Sulphur-bridged Sesquiterpenes, Mintsulphide and Isomintsulphide by Alkyl-lithium

DOI: 10.1039/c39810000127

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Journal of the Chemical Society. Chemical communications p. 127 - 128 (1981)

Update date:2022-09-26

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Authors:

Uyehara, Tadao

Ohnuma, Toshio

Saito, Takashi

Kato, Tadahiro

Yoshida, Toshoi

Takahashi, Katsuhiro

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Article abstract of DOI:10.1039/c39810000127

Reaction of the methylsulphonium salts of mintsulphide (1) and isomintsulphide (2) with methyllithium gives the desulphurization products, via the biradical intermediates, and the <2,3>sigmatropic rearrangement products.

Full text of DOI:10.1039/c39810000127

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