Characterization with 95Mo, 17O, 1H NMR and EPR of alkylperoxo, alkoxo, peroxo and diolo molybdenum (VI) complexes formed in the course of catalytic epoxidation of cyclohexene with organic hydroperoxides

Article abstract of DOI:10.1016/0304-5102(93)87043-8

Using ⁹⁵Mo, ¹H, ¹⁷O NMR and EPR, we have characterized molybdenum(VI) complexes formed in the course of catalytic epoxidation of cyclohexene with tert-butyl and cumene hydroperoxides. Dioxobis(acetylacetonato)molybdenum(VI