Characterization with 95Mo, 17O, 1H NMR and EPR of alkylperoxo, alkoxo, peroxo and diolo molybdenum (VI) complexes formed in the course of catalytic epoxidation of cyclohexene with organic hydroperoxides

DOI: 10.1016/0304-5102(93)87043-8

Source and publish data:

Journal of molecular catalysis p. 329 - 346 (1993)

Update date:2022-08-02

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Authors:

Talsi Talsi

Klimov Klimov

Zamaraev

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Article abstract of DOI:10.1016/0304-5102(93)87043-8

Using ⁹⁵Mo, ¹H, ¹⁷O NMR and EPR, we have characterized molybdenum(VI) complexes formed in the course of catalytic epoxidation of cyclohexene with tert-butyl and cumene hydroperoxides. Dioxobis(acetylacetonato)molybdenum(VI

Full text of DOI:10.1016/0304-5102(93)87043-8

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