
Chemistry Letters p. 409 - 412 (1983)
Update date:2022-08-04
Topics: allylsilanes iodotrimethylsilane Trimethylsilyl trifluoromethanesulfonate
Sakurai, Hideki
Sakata, Yasuyuki
Hosomi, Akira
Iodotrimethylsilane and trimethylsilyl triflate activate selectively the C-Cl bond rather than the C-O bond of α-chloro ethers and catalyze the allylation with allylsilanes to give the corresponding homoallyl ether effectively in good yield.
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