REACTIONS OF ALLYLSILANES WITH α-CHLORO ETHERS CATALYZED BY IODOTRIMETHYLSILANE OR TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE. SYNTHESIS OF HOMOALLYL ETHERS

DOI: 10.1246/cl.1983.409

Source and publish data:

Chemistry Letters p. 409 - 412 (1983)

Update date:2022-08-04

Topics: allylsilanes iodotrimethylsilane Trimethylsilyl trifluoromethanesulfonate

Authors:

Sakurai, Hideki

Sakata, Yasuyuki

Hosomi, Akira

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Article abstract of DOI:10.1246/cl.1983.409

Iodotrimethylsilane and trimethylsilyl triflate activate selectively the C-Cl bond rather than the C-O bond of α-chloro ethers and catalyze the allylation with allylsilanes to give the corresponding homoallyl ether effectively in good yield.

Full text of DOI:10.1246/cl.1983.409

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