Regioselective Diels-Alder Reaction of 2-Substituted Acrylonitriles with Cyclic Dienones and Hydrolytic Ring Cleavage of the Adducts

DOI: 10.1021/jo00334a009

Source and publish data:

Journal of Organic Chemistry p. 4152 - 4157 (1981)

Update date:2022-07-30

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Authors:

Oku, Akira

Hasegawa, Hiroshi

Shimadzu, Hidetaka

Nishimura, Jun

Harada, Toshiro

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Article abstract of DOI:10.1021/jo00334a009

The reactions of 2-substituted acrylonitriles R¹R²C=C(X)CN (1, where R¹=R²=H, X=OCOCH2Cl, OCOPh, OCOOEt, OCOCH3; or 8, where X=Cl) with hexamethylcyclohexa-2,4-dienone (2) proceeded with a high regioselectivity

Full text of DOI:10.1021/jo00334a009

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