A Stereoselective Approach to Acyclic Systems via Condensations of α-Lithiosulfinyl Carbanions and Aldehydes

DOI: 10.1021/jo00333a045

Source and publish data:

Journal of Organic Chemistry p. 4101 - 4103 (1981)

Update date:2022-08-05

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Authors:

Williams, David R.

Phillips, James G.

Huffman, John C.

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Article abstract of DOI:10.1021/jo00333a045

The stereochemical outcome of condensations of α-lithiosulfinyl carbanions with aldehydes is presented, and demonstrates useful methodology for generating 1,2-asymmetry, as well as construction of 1,3-asymmetric relationships in acyclic systems.

Full text of DOI:10.1021/jo00333a045

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