PHOTOCHEMICAL GENERATION OF TETRAMETHYLDISILENE AND PHOTOINDUCED 1,2-SILYL-MIGRATION

DOI: 10.1016/S0040-4039(01)82924-5

Source and publish data:

Tetrahedron Letters p. 2417 - 2420 (1981)

Update date:2022-09-26

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Authors:

Nakadaira, Yasuhiro

Otsuka, Tatsuo

Sakurai, Hideki

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Article abstract of DOI:10.1016/S0040-4039(01)82924-5

Described herein is the first clear evidence of the photochemical generation of tetramethyldisilene which can be efficiently trapped by dienes.An intriguing 1,2-photo-induced silyl migration is also reported.

Full text of DOI:10.1016/S0040-4039(01)82924-5

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