SYNTHESIS OF OPTICALLY ACTIVE FORMS OF METHYL (E)-2,4,5-TETRADECATRIENOATE, THE PHEROMONE OF THE MALE DRIED BEAN BEETLE

DOI: 10.1016/S0040-4020(01)92450-0

Source and publish data:

Tetrahedron p. 1343 - 1347 (1981)

Update date:2022-08-05

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Authors:

Mori, Kenji

Nukada, Tomoo

Ebata, Takahashi

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Article abstract of DOI:10.1016/S0040-4020(01)92450-0

Both enantiomers of methyl (E)-2,4,5,-tetradecatrienoate were synthesized with 125-127percent the rotatory power of the natural product which was isolated as the pheromone of Acanthoscelides obtectus.The absolute configuration of the levorotatory natural pheromone was confirmed to be R.

Full text of DOI:10.1016/S0040-4020(01)92450-0

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