
Tetrahedron p. 1691 - 1696 (1981)
Update date:2022-08-02
Topics:
Castellanos, L.
Gateau-Olesker, A.
Panne-Jacolot, F.
Cleophax, J.
Gero, S.D.
Epoxides 7,8 and 9 have been prepared from D and L-xylose, and used for the synthesis of a precursor of ent-(11-oxa)PG 19 and of 9,13- and 7,11-dioxaprostanoiec acids 28 and 31.The site of the opening of the epoxides 7 and 9 with the carbanion derived from bis-(phenylthio)methane and with LiAlH4 is show by establishing structures of the products 11, 12, 20 et 21 by (13)CNMR spectroscopy.
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Doi:10.1016/S0022-328X(00)85765-4
(1981)Doi:10.1016/j.tet.2009.09.020
(2009)Doi:10.1021/acsmedchemlett.0c00353
(2020)Doi:10.1023/B:JTAN.0000032269.12381.42
(2004)Doi:10.1021/ol048433k
(2004)Doi:10.1021/jo00341a028
(1982)