Bulletin of the Chemical Society of Japan p. 2543 - 2544 (1981)
Update date:2022-09-26
Topics:
Matsuura, Sadao
Sugimoto, Takashi
The C-6 configuration of (-)-6-methyltetrahydropterin, produced by enzymic reduction of the 7,8-dihydro precursor, is shown to be S by a synthesis.Condensation of 2,4-diamino-5-bromo-6-hydroxypyrimidine with (S)-1,2-propanediamine gave (S)-6-methyltetrahydropterin.Examination of CD spectra of the 6-methyltetrahydropterins from the two origins led to the above conclusion.
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Doi:10.1016/S0040-4039(01)90563-5
(1981)Doi:10.1021/ol052563r
(2006)Doi:10.1016/S0040-4020(99)00096-4
(1999)Doi:10.1021/ja01175a602
(1949)Doi:10.1021/om00073a020
(1983)Doi:10.1246/bcsj.54.2672
(1981)
