Photogeneration of Highly Electrophilic Benzoylketene from Dibenzoyldiazomethane in Aqueous Solvents: Reaction with Amino Acids and DNA Cleavage

DOI: 10.1016/00404-0399(50)1040O-

Source and publish data:

Tetrahedron Letters p. 5363 - 5366 (1995)

Update date:2022-08-02

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Authors:

Nakatani, Kazuhiko

Shirai, Junya

Tamaki, Ryo

Saito, Isao

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Article abstract of DOI:10.1016/00404-0399(50)1040O-

Photoirradiation of dibenzoyldiazomethane in the presence of amino acid derivatives in aqueous solutions efficiently produced the addition products through a reaction with photogenerated benzoylketene.Efficient DNA cleavage was observed with a dibenzoyldiazomethane derivative, possessing a cationic side chain under photoirradiation conditions.

Full text of DOI:10.1016/00404-0399(50)1040O-

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