Journal of Organometallic Chemistry p. 281 - 291 (1981)
Update date:2022-07-30
Topics: Synthesis Nucleophilic substitution Anhydrous conditions Purification Reaction Conditions Quenching Spectroscopic Characterization Aromatic substitution Organolithium reagent Low-temperature reaction
Chen, Loomis S.
Chen, Grace J.
Tamborski, Christ
An improved method for the synthesis of 3,5-dibromophenyllithium (I) has been developed.The reactions between I and various substrates leads to a variety of substituted compounds e.g. (3,5-Br2C6H3)nX; when n = 1, X = -CO2H, -CHO, -Si(CH3)2Cl, -C(O)C3F7, -C(O)CF2(OCF2CF2)3OC2F5, -C(O)CF(CF3)OC3F7, -C(O)CF(CF3)
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Doi:10.1246/cl.2004.1398
(2004)Doi:10.1039/c39810000793
(1981)Doi:10.1021/jo00340a044
(1982)Doi:10.1055/s-0029-1219923
(2010)Doi:10.1021/jo970145x
(1997)Doi:10.1016/j.tetlet.2006.04.005
(2006)
