3-(Acyloxy)-3-buten-2-ones as Dienophiles in Anthracyclinone Synthesis. An Efficient Route to 4-Demethoxy-7-deoxydaunomycinone Derivatives.

DOI: 10.1021/jo00342a005

Source and publish data:

Journal of Organic Chemistry p. 409 - 412 (1982)

Update date:2022-08-05

Topics:

Authors:

Ardecky, Robert J.

Dominguez, Domingo

Cava, Michael P.

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Article abstract of DOI:10.1021/jo00342a005

Biacetyl has been converted into a series of 3-(acyloxy)-3-buten-2-ones (13-17) which were characterized both spectroscopically and as their crystalline adducts with 1,3-diphenylisobenzofuran.A comparative study has been made of the reaction of these dien

Full text of DOI:10.1021/jo00342a005

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