SUCCESSIVE METHYL MIGRATIONS OCCURING IN THE ACID TREATMENT OF 1-EPOXYETHYL-1,2,2-TRIMETHYL-CYCLOPENTANE DERIVATIVE

DOI: 10.1016/S0040-4039(00)93658-X

Source and publish data:

Tetrahedron Letters p. 1963 - 1966 (1980)

Update date:2022-08-02

Topics:

Authors:

Kitagawa, Isao

Shibuya, Hirotaka

Fujioka, Hiromichi

Yamamoto, Yoshio

Kajiwara, Akiharu

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)93658-X

Acid treatment of (1R,3S,1'S)-1-(1',2'-epoxyethyl)-1,2,2-trimethyl-3-acetoxymethyl-cyclopentane (6) has been shown to yield three products (8, 9, 10), among which 8 and 9 are 1-oxa-bicyclo<3.3.0>octane derivatives formed via successive methyl migrations followed by an oxorane ring closure.

Full text of DOI:10.1016/S0040-4039(00)93658-X

Products guided by the article

Product name:2-Phenyl-butyric acid (R)-1-((1R,3S)-3-acetoxymethyl-1,2,2-trimethyl-cyclopentyl)-ethyl ester

Cas No:80226-82-0

R&D Labs maybe for 80226-82-0

Jiacheng-Chem Enterprises Limited(expird)

Contact:86-571-86711508

Address:19 Floor, CIBC Holley International Building, No. 198,Wuxing Road, Hangzhou, China,310020
Luoyang Aoda chemical Co.,Ltd.

Contact:+86-379-67518785 67516588

Address:MiaoWan industry district,YanShi City,Henan,China
Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
Kunshan Yalong Trading Co,.Ltd

Contact:86-512-57621185

Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China

Relevant to this article

Correlation of the Rate of Thermal Cis-Trans Isomerization of p-Nitro-p'-dialkylaminoazobenzenes with Solvent Z Value Applied To Study Polarity in Aqueous Surfactant Solutions

Doi:10.1021/ja00370a048
(1982)
Origins of Regio- and Stereoselectivity in Additions of Phenylselenenyl Chloride to Allylic Alcohols and the Applicability of These Additions to a Simple 1,3-Enone Transposition Sequence

Doi:10.1021/jo00346a022
(1982)
η²-BENZOPHENOZIRCONOCEN, EIN MODELL FUER DAS REACTIONSVERHALTEN EINES METALLAOXIRANS?

Doi:10.1016/S0022-328X(00)82564-4
(1982)
A concise synthesis of (±)-sporochnol A

Doi:10.1081/SCC-200034823
(2004)
General methods for alkaloid synthesis. Total synthesis of racemic lycoramine

Doi:10.1021/jo00347a029
(1982)
Novel and highly selective conversion of alcohols and thiols to alkyl nitrites with triphenylphosphine/2,3-dichloro-5,6-dicyanobenzoquinone/Bu ₄NNO₂ system

Doi:10.1055/s-2004-829122
(2004)

Article Doi