Synthesis of (+/-)-Actinidine by an Intramolecular Cycloaddition Process

DOI: 10.1039/P19810001909

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1909 - 1912 (1981)

Update date:2022-09-26

Topics:

Authors:

Davies, Lyn B.

Greenberg, Sydney G.

Sammes, Peter G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19810001909

A new synthesis of (+/-)-actinidine (1), which relies on intramolecular cycloaddition of an acetylene across a pyrimidine ring, is described.Preparation of 5-(hept-5-yn-2-yl)-4,6-dihydroxypyrimidine (2) followed by thermolysis afforded 1-hydroxyactinidine

Full text of DOI:10.1039/P19810001909

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:4-hydroxy-5-(pent-4-ynyl)-2-phenylpyrimidin-6(1H)-one

Cas No:80250-05-1

R&D Labs maybe for 80250-05-1

Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Shanghai Hongbang Medical Technology CO.,. Ltd

Contact:13671516988 /18917636693

Address:Room1, No67 Building, Yongde Road369, Wujing Town, Minhang Districy, Shanghai CIty, China.
ZCIC INTERNATIONAL LTD

Contact:+86-512-56795332

Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
Chengdu ZY Biochemical Technology Co., LTD

Contact:0086-28-88680086

Address:170 Qingpu Road, Shouan Town, Pujiang County
zhangjiagang bonded areas banggao co;ltd

website:http://www.shunchangchem.com

Contact:0086-13921972933

Address:Dongsha Chemical Zone.Zhangjiagang, Jiangsu Province

Relevant to this article

Dendronized protein polymers: Synthesis and self-assembly of monodisperse cylindrical macromolecules

Doi:10.1021/ja046965q
(2004)
Relations between ⁷⁷Se NMR chemical shifts of (phenylseleno)-benzenes and their molecular structures derived from nine X-ray crystal structures

Doi:10.1039/b211130f
(2003)
A New Thermal Rearrangement in the 4-Isoxazoline System. Some Chemical and Stereochemical Properties of a Benzodiazepine Oxide-Ethyl Propiolate Adduct

Doi:10.1021/ja00369a039
(1982)
Evolution of N-Heterocycle-Substituted Iodoarenes (NHIAs) to Efficient Organocatalysts in Iodine(I/III)-Mediated Oxidative Transformations

Doi:10.1002/adsc.201901356
(2020)
Acylative Cleavage of Ethers Catalyzed by Triorganotin Halides and Palladium(II) Complexes

Doi:10.1021/jo00346a015
(1982)
General Base Catalysis, Structure-Reactivity interactions, and Merging of Mechanisms for Elimination Reactions of (2-Arylethyl)quinuclidinium Ions

Doi:10.1021/ja00371a024
(1982)

Article Doi