Synthesis of (+/-)-Actinidine by an Intramolecular Cycloaddition Process

DOI: 10.1039/P19810001909

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1909 - 1912 (1981)

Update date:2022-09-26

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Authors:

Davies, Lyn B.

Greenberg, Sydney G.

Sammes, Peter G.

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Article abstract of DOI:10.1039/P19810001909

A new synthesis of (+/-)-actinidine (1), which relies on intramolecular cycloaddition of an acetylene across a pyrimidine ring, is described.Preparation of 5-(hept-5-yn-2-yl)-4,6-dihydroxypyrimidine (2) followed by thermolysis afforded 1-hydroxyactinidine

Full text of DOI:10.1039/P19810001909

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