Reaction of triorgano(triorganogermyl)silanes with alkaly-metal allyl alcoholates

Article abstract of DOI:10.1080/00397919208055424

Reaction of the lithium alcoholates of 1-vinylcyclohexanol (2a) (±)-linalool (2b), and 1-octen-3-ol (2c) with (dimethylphenylgermyl)trimethylsilane (3a) gave selective the corresponding allyldimethylphenylgermane derivatives (5a,c,e). Similar treatment with dimethylphenyl(trimethylgermyl)silane (3b) gave mixtures of the allyltrimethylgermanes (5b,d,f) and allyldimethylphenylsilanes (7b,d,f), whereas use of the potassium alcoholates afforded selectively 5b,d,f.

Full text of DOI:10.1080/00397919208055424

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Synthetic Communications: An
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Reaction of
Triorgano(Triorganogermyl)Silanes
with Alkali-Metal Allyl
Aicoholates
Mikio Kabaki a , Sumie Inoue a & Yoshiro Sato a
a Faculty of Pharmaceutical Sciences , Nagoya City
University , Tanabe-dori, Mizuho-ku, Nagoya, 467,
Japan
Published online: 05 Dec 2006.
To cite this article: Mikio Kabaki , Sumie Inoue & Yoshiro Sato (1992) Reaction of
Triorgano(Triorganogermyl)Silanes with Alkali-Metal Allyl Aicoholates, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 22:3, 459-466, DOI: 10.1080/00397919208055424
To link to this article: http://dx.doi.org/10.1080/00397919208055424
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