Reaction of triorgano(triorganogermyl)silanes with alkaly-metal allyl alcoholates

DOI: 10.1080/00397919208055424

Source and publish data:

Synthetic Communications p. 459 - 466 (1992)

Update date:2022-08-04

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Authors:

Kabaki Kabaki

Inoue Inoue

Sato Sato

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Article abstract of DOI:10.1080/00397919208055424

Reaction of the lithium alcoholates of 1-vinylcyclohexanol (2a) (±)-linalool (2b), and 1-octen-3-ol (2c) with (dimethylphenylgermyl)trimethylsilane (3a) gave selective the corresponding allyldimethylphenylgermane derivatives (5a,c,e). Similar treatment with dimethylphenyl(trimethylgermyl)silane (3b) gave mixtures of the allyltrimethylgermanes (5b,d,f) and allyldimethylphenylsilanes (7b,d,f), whereas use of the potassium alcoholates afforded selectively 5b,d,f.

Full text of DOI:10.1080/00397919208055424

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