Journal of Organic Chemistry p. 1641 - 1647 (1982)
Update date:2022-07-30
Topics:
Clive, Derrick L.J.
Anderson, Paul C.
Moss, Neil
Singh, Alok
A variety of allylic halides were treated with Te2- (generated in situ) to afford coupled 1,5-dienes (average yield 78percent for 11 examples).Mechanistic studies establish that bisallylic tellurides are produced, and these decompose into allylic radicals which then dimerize.
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