New Method for Coupling Allylic Halides: Use of Te2- Species

DOI: 10.1021/jo00348a006

Source and publish data:

Journal of Organic Chemistry p. 1641 - 1647 (1982)

Update date:2022-07-30

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Authors:

Clive, Derrick L.J.

Anderson, Paul C.

Moss, Neil

Singh, Alok

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Article abstract of DOI:10.1021/jo00348a006

A variety of allylic halides were treated with Te^2- (generated in situ) to afford coupled 1,5-dienes (average yield 78percent for 11 examples).Mechanistic studies establish that bisallylic tellurides are produced, and these decompose into allylic radicals which then dimerize.

Full text of DOI:10.1021/jo00348a006

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