Synthesis, Molecular Structure, and Reactions of Bis(tetraphenylphosphonium) Hexakis(μ-thiophenolato)-tetrachlorotetraferrate(II), (Ph4P)2. Its Reactions with Dibenzyl Trisulfide and the Synthesis of the 2- and <F4S4(Cl)

Article abstract of DOI:10.1021/ja00371a016

The reaction between FeCl2, (C6H5)4PCl, and KSC6H5 in acetonitrilein at 2:1:3 molar ratio or between ^2- and FeX2 (X = Cl, Br) in a 1:2:4 molar ratio affords in excellent yields the new ^2- clusters.The param