Flash Vacuum Pyrolysis of N-Allyl-Substituted 1,3,4-Oxadiazolin-5-ones

DOI: 10.1021/jo01308a031

Source and publish data:

Journal of Organic Chemistry p. 4065 - 4067 (1980)

Update date:2022-09-26

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Authors:

Padwa, Albert

Caruso, Thomas

Nahm, Steven

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Article abstract of DOI:10.1021/jo01308a031

The flash vacuum pyrolysis of several N-allyl-substituted 1,3,4-oxadiazolin-5-ones generates nitrile imines which rearrange to diazoalkenes via a 3,3-sigmatropic shift.

Full text of DOI:10.1021/jo01308a031

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