Photochemistry of Vinyl Halides. Vinyl Cation from Photolysis of 1,1-Diaryl-2-halopropenes

DOI: 10.1021/jo00133a018

Source and publish data:

Journal of Organic Chemistry p. 2323 - 2328 (1982)

Update date:2022-08-05

Topics: Photolysis Photochemistry Vinyl Cation Vinyl halides

Authors:

Kitamura, Tsugio

Kobayashi, Shinjiro

Taniguchi, Hiroshi

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Article abstract of DOI:10.1021/jo00133a018

Irradiation of 1,1-diaryl-2-halopropenes in methanol gave 1,1-diarylpropenes, 1,1-diarylallenes, 1,2-diaryl-1-methoxypropenes, and 9-methoxy-10-methylphenanthrenes.The propenes are derived from vinyl radicals which are generated by homolytic fission of th

Full text of DOI:10.1021/jo00133a018

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