
Tetrahedron Letters p. 4713 - 4716 (1981)
Update date:2022-08-06
Topics:
Sennyey, Gerard
Mathey, Francois
At room temperature 1-phenyl-2,5-dimethylarsole 1 gives <4+2>cycloadditions with dienophiles whereas at 160 deg C it yields arsenic atoms which react with tolane to give the 1,4-diarsabicyclo<2.2.2>octatriene 8 ; 1,2,5-triphenylarsole 2 is less reactive a
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