Journal of Organic Chemistry p. 2326 - 2332 (1984)
Update date:2022-07-30
Topics:
Ohtsuka, Yasuo
Niitsuma, Setsuko
Tadokoro, Hajime
Hayashi, Toshio
Oishi, Takeshi
Total syntheses of (+/-)-isocaryophyllene and (+/-)-caryophyllene are reported.The key step involves a novel construction of the nine-membered ring in these natural products by a base-induced intramolecular acyl transfer reaction of 13-membered lactam sul
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