REGIOSELECTIVE ALKYLATION via TRIALKYLSTANNYLATION: METHYL α-D-GLUCOPYRANOSIDE

DOI: 10.1016/S0008-6215(00)88063-5

Source and publish data:

Carbohydrate Research p. 207 - 216 (1982)

Update date:2022-08-05

Topics: Alkylation Reagent Chemical Reaction Regioselective alkylation

Authors:

Ogawa, Tomoya

Takahashi, Yukio

Matsui, Masanao

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Article abstract of DOI:10.1016/S0008-6215(00)88063-5

Partial stannylation of methyl α-D-glucopyranoside with (Bu3Sn)2O, and subsequent alkylation with benzyl bromide, allyl bromide, and trityl chloride, afforded the 2,6-disubstituted derivative as one of major products in each case.

Full text of DOI:10.1016/S0008-6215(00)88063-5

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Product name:methyl 3,4,6-tri-O-trityl-α-D-glucopyranoside

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