The Cyclic Voltammetry and Cathodic Reduction of Steroidal Homoallylic Nitro Esters. Dimerization vs. Cyclopropane Formation

DOI: 10.1246/bcsj.55.520

Source and publish data:

Bulletin of the Chemical Society of Japan p. 520 - 526 (1982)

Update date:2022-09-26

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Authors:

Sato, Takeo

Komeichi, Yoshihisa

Kobayashi, Shoichi

Omura, Akira

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Article abstract of DOI:10.1246/bcsj.55.520

The cathodic reduction of homoallylic nitro esters was carried out in DMF-TBAP using platinum electrodes.The reaction was found to be highly dependent on the ester-leaving group: Whereas 6-nitrocholest-5-en-3β-yl acetate (3a) gave a 3,3'-dimer 4, 3β-tosyl

Full text of DOI:10.1246/bcsj.55.520

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