The Cyclic Voltammetry and Cathodic Reduction of Steroidal Homoallylic Nitro Esters. Dimerization vs. Cyclopropane Formation

DOI: 10.1246/bcsj.55.520

Source and publish data:

Bulletin of the Chemical Society of Japan p. 520 - 526 (1982)

Update date:2022-09-26

Topics:

Authors:

Sato, Takeo

Komeichi, Yoshihisa

Kobayashi, Shoichi

Omura, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.55.520

The cathodic reduction of homoallylic nitro esters was carried out in DMF-TBAP using platinum electrodes.The reaction was found to be highly dependent on the ester-leaving group: Whereas 6-nitrocholest-5-en-3β-yl acetate (3a) gave a 3,3'-dimer 4, 3β-tosyl

Full text of DOI:10.1246/bcsj.55.520

Products guided by the article

Product name:5-chloro-6β-nitro-5α-cholestane-3β,19-diol 3-acetate 19-tosylate

Cas No:82033-61-2

R&D Labs maybe for 82033-61-2

ZCIC INTERNATIONAL LTD

Contact:+86-512-56795332

Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.

Contact:86-532-88250866

Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China
Jiangxi Dongxu Chemical Science & Technology Co.,Ltd

Contact:+86-791-86899381

Address:Nanchang, Jiangxi, China
Jinan Kaypharm Chemical Co.,Ltd

Contact:86-0531-86986780

Address:Room101,No189-2,Huayuan Road,Jinan City,Shandong Province
Guangzhou Puho Pharmaceutical Technology Co. Ltd.

Contact:86-20-29848035/29848075

Address:No.166, Chaoyang East Road, Panyu District, Guangzhou City, Guangdong Province

Relevant to this article

PREPARATION AND SYNTHTETIC UTILITY OF CYCLOPROPYL PHENYL SULFIDES

Doi:10.1016/S0040-4039(00)87347-5
(1982)
SYNTHESIS OF 4-SUBSTITUTED-3-ETHOXYCARBONYL(CARBOXY)-1,5-NAPHTHYRIDINES, AND THEIR PROPERTIES AND BIOLOGICAL ACTIVITY

Doi:10.1007/BF00759754
(1982)
Two flavonol glycosides from seeds of Camellia sinensis.

Doi:10.1016/0031-9422(91)85293-9
(1991)
Comparison of heterogeneous B(OⁱPr)₃-MCM-41 and homogeneous B(OⁱPr)₃, B(OEt)₃ catalysts for chemoselective MPV reductions of unsaturated aldehydes and ketones

Doi:10.1016/j.apcata.2012.06.004
(2012)
Asymmetric Photopolymerisation in Chiral Crystals. An Example of a Chiral Resolved Monomer Packing in Two Quasi-enantiomeric Phases

Doi:10.1039/c39820000584
(1982)
2,6-Bis(2-alkylphenyl)-3,5-dimethylphenol as a new chiral phenol with C₂-symmetry. Application to the asymmetric alkylation of aldehydes

Doi:10.1021/jo970747g
(1997)

Article Doi