Asymmetric Photopolymerisation in Chiral Crystals. An Example of a Chiral Resolved Monomer Packing in Two Quasi-enantiomeric Phases

DOI: 10.1039/c39820000584

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Journal of the Chemical Society. Chemical communications p. 584 - 587 (1982)

Update date:2022-08-15

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Authors:

Mil, Jan van

Addadi, Lia

Lahav, Meir

Leiserowitz, Les

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Article abstract of DOI:10.1039/c39820000584

The ability of molecules, chiral by virtue of the presence of an s-butyl group, to display conformational polymorphism has been exploited for the performance of asymmetric syntheses of either sense on the same chiral molecule; this phenomenon is illustrated for the asymmetric solid-state polymerisation of the monomer (R)-(-)-(1).

Full text of DOI:10.1039/c39820000584

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