The Total Synthesis of (+)-Milbemycin β3

DOI: 10.1039/c39850001326

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1326 - 1328 (1985)

Update date:2022-09-26

Topics:

Authors:

Baker, Raymond

O'Mahony, Mary J.

Swain, Christopher J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850001326

We report the total synthesis of (+)-milbemycin β₃ from the optically pure precursors spiroacetal (3) and vinyl iodide (2), and the aromatic aldehyde (4).

Full text of DOI:10.1039/c39850001326

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-[(1E,3E,7E)-(R)-9-((2S,4R,6S,8S,9R)-4-Hydroxy-8,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-1,5,7-trimethyl-nona-1,3,7-trienyl]-4-methoxy-5-methyl-benzoic acid methyl ester

Cas No:82045-56-5

R&D Labs maybe for 82045-56-5

Suzhou Health Chemicals Co., Ltd.

website:http://www.healthchems.com

Contact:13776257979

Address:No. 338, Jingang Avenue,
Zhenjiang Haitong Chemical Industry Co., Ltd.

Contact:+86 (511) 8448-0369

Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
Jiande City Silibase Silicone New Material Manufacture Co., Ltd.

Contact:15967177856

Address:Genglou Industrial Development Area
Suzhou Sinosun Imp.&Exp. Corporation

website:http://www.szsinosun.com

Contact:+86-512-63488895,63488616

Address:No.758 East Jiangling Road Wujiang Economic & Technological Developmenty Zone Jiangsu China
Hebei Think-Do Environment Co., Ltd

website:http://www.thinkdo-environment.com

Contact:0311-86510809

Address:No 6, Shilian Middle Street, Circular Chemical Industry Park

Relevant to this article

Doi:10.1021/ja00379a039
(1982)
Intramolecular [2 + 2] photocycloaddition/thermal fragmentation: Formally "allowed" and "forbidden" pathways toward 5-8-5 ring systems

Doi:10.1021/ja044542i
(2005)
Preparation and structure of the unique silicon(iv) cation [SiF ₃(Me₃tacn)]⁺

Doi:10.1039/b822236c
(2009)
1-Oxaspiro<4.4>nona-3,6,8-trien-2-one: Neuartige Produkte aus Acetylenen und Kohlenmonoxid in Gegenwart von Kobaltcarbonyl

Doi:10.1016/0022-328X(89)88056-8
(1989)
Synthesis of novel thiazolone-based compounds containing pyrazoline moiety and evaluation of their anticancer activity

Doi:10.1016/j.ejmech.2008.09.032
(2009)
Syntheses of RuHCl(CO)(PAr₃)₃ and RuH₂(CO)(PAr₃)₃ Containing various triarylphosphines and their use for arylation of sterically congested aromatic C-H bonds

Doi:10.1021/acs.organomet.6b00540
(2017)

Article Doi