Bulletin of the Chemical Society of Japan p. 924 - 927 (1982)
Update date:2022-08-03
Topics:
Terunuma, Daiyo
Senda, Kazuhisa
Sanazawa, Masato
Nohira, Hiroyuki
Optically active α-amino organosilanes such as benzylmethyl(o- or p-tolyl)silylmethylamine were converted into benzylmethylphenyl(o- or p-tolyl)silane, of which the configurations had been known.From these observations, it was found that (+)- and (-)-benzylmethyl(o- or p-tolyl)silylmethylamine has S and R configuration respectively.Furthermore, the stereochemistry of the reaction of benzylmethyl(methoxy)phenylsilane with some organometallic agents was investigated.
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(1982)Doi:10.1016/S0040-4039(00)82241-8
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