Journal of Organic Chemistry p. 3643 - 3646 (1982)
Update date:2022-08-02
Topics:
Snider, Barry B.
Cordova, Robert
Price, Robert T.
Reaction of CH2O*Me3Al with electron-rich alkenes gives a zwitterion that reacts further to give homoallylic alcohols (ene adducts), allylic alcohols, and the product of cis addition of a hydroxymethyl and a methyl group to the double bond.The stereochemistry and effect of alkene structure on the nature of the reaction are examined.
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