Formation of Tris-chelated Vanadium(IV) Complexes by Interaction of Oxovanadium(IV) with Catecholamines, 3-(3,4-Dihydroxyphenyl)alanine and Related Ligands in Aqeous Solution

DOI: 10.1039/DT9930002057

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2057 - 2064 (1993)

Update date:2022-08-04

Topics:

Authors:

Buglyo, Peter

Dessi, Alessandro

Kiss, Tamas

Micera, Giovanni

Sanna,Daniele

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9930002057

Complex formation between oxovanadium(IV) and a series of o-catecholic ligands was investigated in aqueous solution by EPR and electronic absorption spectroscopy and pH-potentiometry.The reaction scheme involves, besides the normal mono- and bis-catecholato oxovanadium(IV) complexes, also species where the bare vanadium(IV) ion, lacking the oxo ligand, is chelated by three catecholate ligands.A comparative examination of the systems showed that the extent to which the ligands are able to form tris complexes with V^IV, by displacing the oxo group from VO²⁺, may be reasonable interpreted in terms of the electrostatic repulsion between the bis complex and the attacking third ligand molecule and also the base strength of the phenolate groups of the ligands.

Full text of DOI:10.1039/DT9930002057

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(1,2-dihydroxo 3,5-disulfonato benzene) oxo vanadate (IV) ^(2-)

Cas No:82613-88-5

R&D Labs maybe for 82613-88-5

Hubei Xiangxi Chemical Industry Co.,Ltd

Contact:+86-710-3454830

Address:No.7, Daqing East Road, Xiangfan City, Hubei Province, China
Cangzhou Senary Chemical Science-tech Co., Ltd

Contact:+86-317-3563899, 3563699

Address:168 Jinde Road, Cangzhou, Hebei, China
Shandong LuZhou Amino Acid Co., Ltd

Contact:86-539-2218025

Address:yishui economic and technical development zone zhenxing south road
Disynthesis Chemical Technology Co. Ltd.

Contact:+86-571-88194596

Address:Dengyun road 380, Gongshu district, Hangzhou city, China
Xi'an Costrong Pharmaceutical Co., Ltd.

Contact:029- 68576496

Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China

Relevant to this article

Carbonyl and thiocarbonyl compounds. XIX. Intramolecular cyclization of (2-nitroethenyl)aryl N-arylcarbamates: Synthesis of newer series of 3,4-dihydro-2H-1,3-oxazin-2-ones and their antimicrobial activities

Doi:10.1071/CH9821037
(1982)
4-(1,2,4-Triazol-1-yl)- and 4-(3-Nitro-1,2,4-triazol-1-yl)-1-(β-D-2,3,5-tri-O-acetylarabinofuranosyl)pyrimidin-2(1H)-ones. Valuable Intermediates in the Synthesis of Derivatives of 1-(β-D-Arabinofuranosyl)cytosine (Ara-C)

Doi:10.1039/P19820001171
(1982)
SYNTHESE FUER OPTISCH AKTIVE (6R)-SUBSTITUIERTE (5R) CARBAPENEME

Doi:10.1016/S0040-4039(00)87154-3
(1982)
Total synthesis of 6-trans,10-cis and (±)-6-trans,8-cis isomers of leukotriene B

Doi:10.1021/ja00547a600
(1980)
Marine natural products: Parguerol, deoxyparguerol, and isoparguerol. New brominated diterpenes with modified pimarane skeletons from the sea hare Aplysia dactylomela

Doi:10.1021/ja00387a045
(1982)
Exploratory studies aimed at a synthesis of vinigrol. 3. Evaluation of a lactone bridge as a conformational lock

Doi:10.1021/jo0484575
(2005)

Article Doi