A NEW METHOD FOR THE PREPARATION OF α-(PERFLUOROALKYL) CARBONYL AND γ-(PERFLUOROALKYL)-α,β-UNSATURATED CARBONYL COMPOUNDS

DOI: 10.1016/S0040-4039(00)87135-X

Source and publish data:

Tetrahedron Letters p. 1471 - 1474 (1982)

Update date:2022-08-04

Topics:

Authors:

Umemoto, Teruo

Kuriu, Yuriko

Nakayama, Shin-ichi

Miyano, Osamu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)87135-X

RfI(Ph)OSO2CF3 or RfI(Ph)OSO3H smoothly reacted with various trimethylsilyl enol ethers under mild conditions to give α(perfluoroalkyl) carbonyl and γ=)perfluoroalkyl)-α,β-unsaturated carbonyl compounds in high yields.

Full text of DOI:10.1016/S0040-4039(00)87135-X

Products guided by the article

Product name:1-benzoyl-2-(1-morpholino)-3,3,3-trifluoro-1-propene

Cas No:82959-36-2

R&D Labs maybe for 82959-36-2

Dezhou Longteng Chemical Co., Ltd.

website:http://www.sodium-methoxide.cn/

Contact:0086-18866052283

Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
Shanghai Yurui Biotechnology(Anyang) Pharmaceutical Co., Ltd

Contact:+86-0372-3662335 +86-0372-3661988

Address:hanling industrial park anyang
shanghai tuomiao chemicial co.,ltd.

website:https://www.tuomiaochem.com/

Contact:021 - 59853336

Address:shanghai
Hubei Danao Pharmaceutical Co.,Ltd.

website:http://www.danaopharm.com

Contact:+86-719-5251167

Address:Fandan Road,Danjiangkou,Hubei
Zibo Hangyu Biotechnology Development Co., Ltd

Contact:86-15965530500

Address:Room1701, Tianxing Building,Licheng district, jinan, Shandong, China

Relevant to this article

HIGHLY STEREOCONTROLLED REDUCTION OF α'-ALKOXYENONES TO GIVE EITHER THE THREO OR ERYTHRO ALLYLIC 1,2-DIOL. ASSIGNMENT OF THE THREO CONFIGURATION TO THE C-15,C-16 DIOL OF PUMILIOTOXIN B.

Doi:10.1016/S0040-4039(00)87340-2
(1982)
Doi:10.1002/ardp.19592920703
(1959)
Photoreactions of γ,δ-unsaturated chromium carbene complexes

Doi:10.1021/ja9537585
(1996)
A convenient synthesis of 1,2-O-benzylidene and 1,2-O-ethylidene derivatives of carbohydrates

Doi:10.1016/S0008-6215(00)80547-9
(1982)
SYNTHESIS OF SPIRO AND BICYCLIC NULCEOSIDES FROM RIBOSE NITRILE OXIDE WITH DIMETHYL ACETYLENEDICARBOXYLATE

Doi:10.1016/S0040-4039(01)80480-9
(1989)
Regio- and Stereo-selectivity in the Hydrogenation of Aryl Phosphines by Niobium Aryloxide Compounds

Doi:10.1039/c39950000849
(1995)

Article Doi