A NEW METHOD FOR THE PREPARATION OF α-(PERFLUOROALKYL) CARBONYL AND γ-(PERFLUOROALKYL)-α,β-UNSATURATED CARBONYL COMPOUNDS

DOI: 10.1016/S0040-4039(00)87135-X

Source and publish data:

Tetrahedron Letters p. 1471 - 1474 (1982)

Update date:2022-08-04

Topics:

Authors:

Umemoto, Teruo

Kuriu, Yuriko

Nakayama, Shin-ichi

Miyano, Osamu

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Article abstract of DOI:10.1016/S0040-4039(00)87135-X

RfI(Ph)OSO2CF3 or RfI(Ph)OSO3H smoothly reacted with various trimethylsilyl enol ethers under mild conditions to give α(perfluoroalkyl) carbonyl and γ=)perfluoroalkyl)-α,β-unsaturated carbonyl compounds in high yields.

Full text of DOI:10.1016/S0040-4039(00)87135-X

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