Fluorination of Polycyclic Aromatic Hydrocarbons: Charge vs. Frontier Orbital Control in Substitution Reactions of Radical Cations

DOI: 10.1021/jo00189a031

Source and publish data:

Journal of Organic Chemistry p. 2803 - 2807 (1984)

Update date:2022-07-29

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Authors:

King, Patrick F.

O'Malley, Robert F.

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Article abstract of DOI:10.1021/jo00189a031

The anodic fluorination of perylene and pyrene in acetonitrile occurred at potentials consistent with the intermediacy of dications, but that of triphenylene with its radical cation.Fluorination of anthracene compounds at a meso position occurred by the a

Full text of DOI:10.1021/jo00189a031

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