REACTIONS OF SOME OXIRANES WITH RHODIUM(I) AND IRIDIUM(I) SPECIES

DOI: 10.1016/S0022-328X(00)89071-3

Source and publish data:

Journal of Organometallic Chemistry p. 273 - 278 (1982)

Update date:2022-08-05

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Authors:

Osborne, Robert B.

Ibers, James A.

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Article abstract of DOI:10.1016/S0022-328X(00)89071-3

Tetracyanooxirane oxidatively adds to rhodium(I) and iridium(I) species to afford metal(III) compounds.With trans-RhCl(CO)(PPh3)2 a reaction in boiling C6H6 produces RhCl(CN)(OC2(CN)3)(CO)(PPh3)2, a rhodium(III)(cyano)(tricyanoenolato) compound.Characteri

Full text of DOI:10.1016/S0022-328X(00)89071-3

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