Journal of Organometallic Chemistry p. C9 - C12 (1982)
Update date:2022-09-26
Topics:
Clark, G.R.
Hoskins, S.V.
Roper, W.R.
Ru(CO)3(PPh3)2 or Ru(CO)2(PPh3)2 with Hg(CF3)2 gives Ru(CF3)HgCF3)(CO)2(PPh3)2.X-ray crystal structure determination reveals an octahedral geometry and the average C-F distance in the CF3 group which is Ru-bound is 0.1 Angstroem longer than in the CF3 group Hg-bound.This and other Ru-CF3 complexes such as Ru(CF3)Cl(CO)2(PPh3)2 react with aqueous acids converting the CF3 group to a CO group.Difluorocarbene complexes are implicated in these reactions and a crystalline example of such a compound is RuCl2(CF2)(CO)(PPh3)2 derived from Ru(CF3)Cl(CO)(MeCN)(PPh3) and dry HCl gas in benzene solution.RuCl2(CF2)(CO)(PPh3)2 is readily hydrolysed to RuCl2(CO)2(PPh3)2, while Me2NH gives RuCl2(CFNMe2)(CO)(PPh3)2, MeOH gives RuCl2(CFOMe)(CO)(PPh3)2, and ethanediol gives
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