
Chemistry of Heterocyclic Compounds p. 690 - 692 (1982)
Update date:2022-08-05
Topics:
Migalina, Yu. V.
Galla-Bobik, S. V.
Khripak, S. M.
Staninets, V. I.
The reaction of selenium tetrachloride with allylbenzene and allyl phenyl ether proceeds in accordance with the Markownikoff rule to give 1:2 adducts.The use of selenium tetrabromide changes the course of the reaction and leads to the production of a mixture of adducts in accordance with and counter to the Markownikoff rule, as well as products of cyclization of the intermediate monoadducts to 2-bromomethyl-2,3-dihydrobenzoselenophene or 2-bromomethyl-benzo-1,3-selenoxane derivatives.
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