Methylase Models: Intramolecular Alkylation of a Phenol by an Adenosyl Sulphonium Salt

DOI: 10.1039/c39820000698

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 698 - 699 (1982)

Update date:2022-08-05

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Authors:

Vasquez, Peter J.

Coward, James K.

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Article abstract of DOI:10.1039/c39820000698

The newly synthesized adenosylsulphonium ion, (2), undergoes a facile ring closure reaction in aqueous oxyanion buffers; in contrast, amine buffers effect an intermolecular dealkylation in competition with the lyate reaction.

Full text of DOI:10.1039/c39820000698

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