Unusual Products from the Reactions of Anhydrous Hydrogen Chloride with Arylacetylenes

DOI: 10.1021/jo00146a029

Source and publish data:

Journal of Organic Chemistry p. 4975 - 4981 (1982)

Update date:2022-07-29

Topics:

Authors:

Griesbaum, Karl

Rao, V. V. Ramana

Leifker, Gregor

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00146a029

Liquid-phase reactions of anhydrous hydrogen chloride with p-methyl-, p-methoxy-, p-fluoro-, and unsubstituted phenylacetylene afforded cyclic trimers, tetramers, and pentamers of the corresponding arylacetylenes.Phenylacetylene gave additionally 1-methyl-1-phenyl-3-chloroindene.The reactions proceeded via the corresponding HCl diadducts, i.e., via 1-aryl-1,1-dichloroethanes as intermediates.

Full text of DOI:10.1021/jo00146a029

Products guided by the article

Product name:2,10-difluoro-6,12,13a-tris(p-fluorophenyl)-12-methylbenzo<6,7>cycloheptadieno<1,2,3-jk>fluorene

Cas No:83313-84-2

R&D Labs maybe for 83313-84-2

Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China
JinTan Pingsheng Chemical Co.,Ltd

Contact:+86-519-82828200

Address:NO.11Danfengxilu Road,Jintan City,Jiangsu,China
Nantong Baokai Chemical Co., Ltd (Hangzhou Baokai Bio-Chemicals Co.,Ltd.)

Contact:+86-513-83886111

Address:No. 68 Suzhou road ,Binjiang Fine Chemical Industrial Park , Beixin town, Qidong city ,Jiangsu province
Quhua Zhongxing Refrigeration Technology Co.,Ltd.

Contact:+86-5708886618

Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
TAIZHOU XINGCHENG CHEMPHARM CO.,LTD.

Contact:0086-0576-88551200,88886292 ,88880039

Address:B Area. 10 Floor.Yaodadasha. 289#.Shifu Road.Taizhou.Zhejiang.China

Relevant to this article

Stereoselective synthesis and moulting activity of 2,3-diepi-20- hydroxyecdysone and 2,3-diepi-5α-20-hydroxyecdysone

Doi:10.1016/j.tet.2004.02.042
(2004)
Ring-closing metathesis approach to dictyostatin

Doi:10.1021/ol0478279
(2005)
Ground-state equilibrium thermodynamics and switching kinetics of bistable [2]rotaxanes switched in solution, polymer gels, and molecular electronic devices

Doi:10.1002/chem.200500934
(2006)
1.2-DIAZA-4-PHOSPHA-CYCLOPENTANE - 1.5-DIAZA-3.7-DIPHOSPHABICYCLO-<3.3.0>OCTANE N.N'--N.N'-DIMETHYLHYDRAZINE 1.3-DIAZA-5-PHOSPHA-CYCLOHEXANE

Doi:10.1016/0040-4039(81)80062-7
(1981)
Polystyrene-Bearing Cyclopentadienyl Metal Catalysts: Copolymerization of a Styrene Monomer Containing Cyclopentadiene Synthons

Doi:10.1021/ja00407a024
(1981)
Syntheses of erythrinan alkaloids: (±)-Coccolinine, (±)-isococculidine, (±)-coccuvinine, and (±)-cocculidine

Doi:10.1248/cpb.29.396
(1981)

Article Doi