Journal of the Chemical Society. Chemical communications p. 717 - 719 (1992)
Update date:2022-07-29
Topics:
Shaaf, Paul A. van der
Smeets, Wilberth J. J.
Spek, Anthony L.
Koten, Gerard van
At -78 deg C a tetra-organotungsten(VI) complex which decomposes by an Hα-elimination reaction generating a novel tungsten(VI) alkylidene with intramolecular coordination of an amine function; this complex reacts with norbornene to provide a cis-polymer that is the result of an selective ring-opening metathesis.
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