Synlett p. 2771 - 2775 (2004)
Update date:2022-08-05
Topics: Functionalization Protecting groups Stereocontrol Cross-Coupling Reaction Final steps Tandem Reactions Starting Material Selection Wittig Reaction
Oh, Kyungsoo
Parsons, Philip J.
Cheshire, Dave
A stereoselective synthesis of substituted 1,3-dienes has been developed which utilises an Ireland-Claisen rearrangement/silicon-mediated fragmentation sequence. This sequence has been designed to introduce remote centres of asymmetry as well as stereodefined diene systems, and its application to an aziridine system is also described.
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Doi:10.2174/157017809789124867
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(2003)
