A Nonresolutive Approach to the Preparation of Configurationally Pure Difunctional Molecules

DOI: 10.1021/jo00148a046

Source and publish data:

Journal of Organic Chemistry p. 5418 - 5420 (1982)

Update date:2022-08-03

Topics:

Authors:

Chillous, Sandra E.

Hart, David J.

Hutchinson, Douglas K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00148a046

Treatment of menthone (5) with organometallic reagents affords axial tertiary alcohols of type 6 with high diastereoselectivity.Propionate 12, derived from trans-11, undergoes an enolate Claisen rearrangement with complete transfer of chirality.The use of

Full text of DOI:10.1021/jo00148a046

Products guided by the article

Product name:(2S,3R)-4-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-2,3-dimethyl-butyric acid

Cas No:83860-22-4

R&D Labs maybe for 83860-22-4

Changzhou Hopschain Chemical Co.,Ltd

website:http://www.hopschem.cn/products.html

Contact:86-519-85528066

Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China
Jiaxing Taixin Pharmaceutical Chemical Co., Ltd

Contact:0573-82613601

Address:Chemical Park, Jiaxing, Zhejiang, China
Shandong Bolode Bio-Technology Co., LTD

Contact:+86-0531-58966870

Address:136 Jingyi Road,Huaiyin District,Jinan,Shandong,China
Zhejiang Allied Chemical Co.,Ltd

Contact:18967038207

Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
Greenutra Resource Inc

website:http://www.greenutra.cn

Contact:0086-411-39553357

Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China

Relevant to this article

Hydrogenation of trimetallic clusters of the iron triad containing bridging carbyne ligands. Reductive cleavage of a triply bridging carbyne

Doi:10.1021/om00074a003
(1983)
Synthesis of N⁷-hydroxy- and N⁷-methoxycephalosporins

Doi:10.1248/cpb.30.3061
(1982)
Study of the Conformation of Novel N-Nitrosothioureas by High-Field Nitrogen-15 and Carbon-13 Nuclear Magnetic Resonance Spectroscopy Employing Specifically Labeled Compounds

Doi:10.1021/jo00152a020
(1983)
A STEREOCONTROLLED SYNTHESIS OF (2R,3R,5R,13S,14R)-(+)-APLIDIASPHINGOSINE, A MARINE TERPENOID

Doi:10.1016/S0040-4039(00)87623-6
(1982)
Doi:10.1021/ja01872a013
(1939)
Stereochemistry of 3-oxo-5-phenylcyclopentanecarboxylic acids, V: On the stereoselective synthesis of the stereomeric 5-phenyldihydrosarcomycines

Doi:10.1002/ardp.19823151008
(1982)

Article Doi