A Nonresolutive Approach to the Preparation of Configurationally Pure Difunctional Molecules

DOI: 10.1021/jo00148a046

Source and publish data:

Journal of Organic Chemistry p. 5418 - 5420 (1982)

Update date:2022-08-03

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Authors:

Chillous, Sandra E.

Hart, David J.

Hutchinson, Douglas K.

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Article abstract of DOI:10.1021/jo00148a046

Treatment of menthone (5) with organometallic reagents affords axial tertiary alcohols of type 6 with high diastereoselectivity.Propionate 12, derived from trans-11, undergoes an enolate Claisen rearrangement with complete transfer of chirality.The use of

Full text of DOI:10.1021/jo00148a046

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