A NEW METHOD FOR THE SYNTHESIS OF α-L-THREOFURANOSIDES FROM ACYCLIC PRECURSOR

DOI: 10.1246/cl.1982.1555

Source and publish data:

Chemistry Letters p. 1555 - 1558 (1982)

Update date:2022-09-26

Topics:

Authors:

Mukaiyama, Teruaki

Sugaya, Toru

Marui, Shogo

Nakatsuka, Takashi

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Article abstract of DOI:10.1246/cl.1982.1555

Stereoselective alkoxylation of acyclic precursor, (2S,3S)-2,3-O-isopropylidene-4-chloro-4-phenylthiobutyric acid methyl ester (3) in the presence of SnCl2-AgClO4, followed by Pd(OAc)2 promoted cyclization gave α-L-threofuranosides in good yields.

Full text of DOI:10.1246/cl.1982.1555

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