Reactions of Cyanoalkenes with a Tungsten Hydrazido(2-) Complex: the X-Ray Crystal Structure of >, a Bromotricyanoprop-2-enylideneamino-complex

DOI: 10.1039/c39820000736

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 736 - 738 (1982)

Update date:2022-08-04

Topics:

Authors:

Colquhoun, Howard M.

Crease, Allan E.

Taylor, Stephen A.

Williams, David J.

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Article abstract of DOI:10.1039/c39820000736

Cyanoalkenes react with the dinitrogen-derived hydrazido(2-) complex ⁺Br^- (1) to form either vinyldiazenido-complexes or, after loss of the hydrazido(2-) ligand, to form nitrile-derived methyleneamino-complexes; the product of reaction with tetracyanoethyleneis a bromotricyanoprop-2-enylideneamino-complex which has been characterised by single-crystal X-ray analysis.

Full text of DOI:10.1039/c39820000736

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