A New Super-Electrophile: α-(Phenylsulfonyl)maleic Anhydride

DOI: 10.1021/jo00273a015

Source and publish data:

Journal of Organic Chemistry p. 2852 - 2854 (1989)

Update date:2022-08-04

Topics:

Authors:

Ramezanian, Merrikh

Abdelkader, Mohamed

Padias, Anne Buyle

Hall, H. K.

Brois, Stanley J.

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Article abstract of DOI:10.1021/jo00273a015

α-(Phenylsulfonyl)maleic anhydride is synthesized by oxidation of α-(phenylthio)maleic anhydride.The title compound reacts extremely fast with isoprene, 2,3-dimethylbutadiene, and chloroprene to form the expected <4 + 2> cycloadducts.With cyclopentadiene,

Full text of DOI:10.1021/jo00273a015

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