The Preparation of Optically Active β-Keto Sulfoxides by Means of an Enantiomer-differentiating Reaction of α-Lithio Aryl Methyl Sulfoxides with Chiral Carboxylates

DOI: 10.1246/bcsj.54.1143

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1143 - 1150 (1981)

Update date:2022-08-04

Topics: Enantiomer Chiral Optically active Substituted Preparation Lithiation Functional group β-Keto Sulfoxides

Authors:

Kunieda, Norio

Suzuki, Akira

Kinoshita, Masayoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.54.1143

The reaction of α-lithio aryl methyl sulfoxides with a limited amount of chiral carboxylates (R²-CO-O-R^*) was found to be an enantiomer-differentiating reaction, affording the corresponding optically active β-keto sulfoxides (3), tog

Full text of DOI:10.1246/bcsj.54.1143

Products guided by the article

Product name:1-((R)-Toluene-4-sulfinyl)-undecan-2-one

Cas No:85617-02-3

R&D Labs maybe for 85617-02-3

Chongqing maohuan Chemicals Co., Ltd

website:http://www.bschem.com

Contact:+86 13996103726

Address:Chongqing Nan'an District Tu Town
Accendatech Co., LTD

Contact:+86-22-83718541

Address:32th Floor, Rongqiao Center Intersection of Changjiang Road and Nankai Six Road Nankai District Tianjin 300102, China
Liao Cheng All Win Chemicals Co.,LTD

Contact:86+0635-2991582

Address:Room 402,Unit 1,No.27 building.Zhong tong shi dai haoyuan,liaocheng city,Shan dong Province.China
Chinapeptides Co,. Ltd

Contact:+86-021-50792271

Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Shandong LuZhou Amino Acid Co., Ltd

Contact:86-539-2218025

Address:yishui economic and technical development zone zhenxing south road

Relevant to this article

Intramolecular Cycloaddition Reactions of in situ Generated Azoalkenes; Synthesis of Pyrrolo<1,2-b>pyridazine Derivatives from α-Haloketone 4-Pentenoylhydrazones

Doi:10.1055/s-1983-30263
(1983)
Copper(II)-catalyzed synthesis of pyrimidines from propargylic alcohols and amidine: A propargylation-cyclization-oxidation tandem reaction

Doi:10.1055/s-0030-1259954
(2011)
Cyclopolimerization and Regioselective Synthesis of Vinyl Itaconates

Doi:10.1021/jo00366a023
(1986)
Synthesis of a phenyl thio-ss-D-galactopyranoside library from 1,5-difluoro-2,4-dinitrobenzene: Discovery of efficient and selective monosaccharide inhibitors of galectin-7

Doi:10.1039/b502354h
(2005)
Enantiospecific synthesis of (-)-trachyspic acid

Doi:10.1039/b504258e
(2005)
Facile synthesis of (S)-gizzerosine - A potent inducer of gizzard erosion in chicks - Using successive zinc-mediated and palladium-catalyzed coupling reactions

Doi:10.1055/s-2005-918447
(2005)

Article Doi