The Preparation of Optically Active β-Keto Sulfoxides by Means of an Enantiomer-differentiating Reaction of α-Lithio Aryl Methyl Sulfoxides with Chiral Carboxylates

DOI: 10.1246/bcsj.54.1143

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1143 - 1150 (1981)

Update date:2022-08-04

Topics: Enantiomer Chiral Optically active Substituted Preparation Lithiation Functional group β-Keto Sulfoxides

Authors:

Kunieda, Norio

Suzuki, Akira

Kinoshita, Masayoshi

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Article abstract of DOI:10.1246/bcsj.54.1143

The reaction of α-lithio aryl methyl sulfoxides with a limited amount of chiral carboxylates (R²-CO-O-R^*) was found to be an enantiomer-differentiating reaction, affording the corresponding optically active β-keto sulfoxides (3), tog

Full text of DOI:10.1246/bcsj.54.1143

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