Journal of Organic Chemistry p. 2318 - 2321 (1983)
Update date:2022-07-29
Topics:
Schultz, Arthur G.
Dittami, James P.
A formal total synthesis of dl-clovene (9) is described.The synthesis is highlighted by the efficient intramolecular alkylation of trisubstituted cyclohexenone 11b to give 5-(2-ethylallyl)-1-methylbicyclo<3.3.1>non-2-en-4-one (13b) in 80percent isolated yield.The preparation of 11b follows an alkylation route starting with the enol ether 3 of cyclohexane-1,3-dione.
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