Tetrahedron Letters p. 725 - 728 (1983)
Update date:2022-08-04
Topics:
Reutrakul, Vichai
Rukachaisirikul, Vatcharin
Alkylation of lithio fluoromethyl phenyl sulfoxide 2 gave the alkylated products in high yields.Pyrolysis of the products led to vinyl fluorides in excellent yields.The reaction of 2 with carbonyl compounds led to the corresponding β-hydroxy-α-fluoromethyl phenyl sulfoxides.Pyrolysis of some of the sulfoxides gave fluoromethylketones in moderate yields.
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