Tetrahedron p. 861 - 866 (1983)
Update date:2022-09-26
Topics: Aldehyde Reaction Experimental Lead(IV) Acetate Enol Silyl ether
Rubottom, George M.
Marrero, Roberto
Gruber, John M.
The treatment of aldehyde enol silyl ethers 1 with lead(IV)acetate (LTA) using methylene chloride as solvent gives rise to the production of α-acetoxy aldehydes 2 and glycolic ester derivatives 3 or enals 5.Structrural variations in 1 are used to explained the divergent trends.When 1 is treated with LTA/KOAc/AcOH, high yields of the corresponding α-acetoxy aldehydes 2 are obtained with the formation of 3 and 5 being subverted.
View MoreHefei TNJ chemical industry co.,ltd
website:https://www.tnjchem.com
Contact:+86-551-65418695
Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
FOSHAN NANHAI ZHONGNAN PHARMACEUTICAL FACTORY
Contact:0086-0757-85609331
Address:XIAHENGTIAN INDUSTRIAL ZONE,SHAYONG VILLAGE,LISHUI TOWN
website:http://www.arromax.com
Contact:+86-0512-62959601 skype:aimmezhang
Address:Suite 401, Bldg A3, 218 Xinghu St.Suzhou Industrial Park 215123, P.R. China
Hangzhou yi lu biont technology Co., LTD
Contact:+86-571-88152630
Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
Shijiazhuang City Xiehe Pharmaceutical Co., Ltd
Contact:+86-311-80817929
Address:Shangzhuang,Shijiazhuang,China
Doi:10.1016/j.tetasy.2005.06.033
(2005)Doi:10.1016/j.tetlet.2005.03.190
(2005)Doi:10.1055/s-1983-30360
(1983)Doi:10.1016/j.tet.2005.07.087
(2005)Doi:10.1016/j.tetlet.2006.05.006
(2006)Doi:10.1021/jo00168a031
(1983)
