Orientation Effects on the Rate and Equilibrium Constants for Formation and Decomposition of Tetrahedral Intermediates

DOI: 10.1021/ja00357a027

Source and publish data:

Journal of the American Chemical Society p. 6138 - 6141 (1983)

Update date:2022-09-26

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Authors:

Santry, Linda J.

McClelland, Robert A.

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Article abstract of DOI:10.1021/ja00357a027

A kinetic study is reported of the hydrolysis of the ortho ester 2 obtained by exchange of exo,exo-2,3-norbornanediol and trimethyl orthobenzoate.As a typical of this type of ortho ester, a change in slow step is observed between high pH and low pH, and r

Full text of DOI:10.1021/ja00357a027

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