Orientation Effects on the Rate and Equilibrium Constants for Formation and Decomposition of Tetrahedral Intermediates

DOI: 10.1021/ja00357a027

Source and publish data:

Journal of the American Chemical Society p. 6138 - 6141 (1983)

Update date:2022-09-26

Topics:

Authors:

Santry, Linda J.

McClelland, Robert A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00357a027

A kinetic study is reported of the hydrolysis of the ortho ester 2 obtained by exchange of exo,exo-2,3-norbornanediol and trimethyl orthobenzoate.As a typical of this type of ortho ester, a change in slow step is observed between high pH and low pH, and r

Full text of DOI:10.1021/ja00357a027

Products guided by the article

Product name:(1R,2R,6S,7S)-4-Methoxy-4-phenyl-3,5-dioxa-tricyclo[5.2.1.0^2,6]decane

Cas No:86287-25-4

R&D Labs maybe for 86287-25-4

SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
SuZhou Hua-Emy Chemical Import and Export Co., LTD.

Contact:+86-512-88804994; +86-512-88804550;

Address:710, Building B, International Trade Center, 12 Huanghelu, Changshu, Jiangsu,China
ZHANGJIAGANG FREE TRADE ZONE YONG HAN INTERNATIONAL TRADING CO., LTD(expird)

Contact:86 512 57910558

Address:qianjin M road
Guangzhou Chemical Reagent Factory

Contact:+86-20-8435 9820 or 8435 7345

Address:Southern Guangzhou, Guangdong, China
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu

Relevant to this article

Development of a green and sustainable manufacturing process for gefapixant citrate (MK-7264). Part 5: Completion of the api free base via a direct chlorosulfonylation process

Doi:10.1021/acs.oprd.0c00247
(2020)
Synthesis and characterization of novel fluorescent N-glycoconjugates

Doi:10.1016/j.tet.2005.07.006
(2005)
A New Synthetic Method of Preparing Iodohydrin and Bromohydrin Derivatives through in Situ Generation of Hypohalous Acids from H5IO6 and NaBrO3 in the Presence of NaHSO3

Doi:10.1021/jo00098a012
(1994)
Synthesis of the branched-chain sugar aceric acid: A unique component of the pectic polysaccharide rhamnogalacturonan-II

Doi:10.1021/jo051012b
(2005)
Novel synthesis and anti-inflammatory activities of 2,5-disubstituted- dioxacycloalkanes

Doi:10.1016/j.bmc.2005.05.032
(2005)
Probing the electronic factors responsible for the cyclic electron-transfer induced isomerism fac ? mer: Synthesis, electrochemical and spectroscopic studies of fac-[Mn(CO)₃(L′-L′)L] ^0/+ complexes

Doi:10.1016/j.ica.2005.07.012
(2005)

Article Doi